Do you have a surge tank? Are you sure you're using a fuel cap type of lid on your radiator? The cap on the radiator should not be vented, as it should push any overflow coolant into the surge tank. The surge tank will have a vented cap. If you are using a fuel cap on the radiator then it is probably vented. When any significant pressure builds up in the radiator as the coolant warms up, the vent on the fuel cap you are using could be causing the leak.
Corey